Structure of [NH3(CH2)4NH3]2P4O12·2H2O
Identifieur interne : 001A85 ( Main/Exploration ); précédent : 001A84; suivant : 001A86Structure of [NH3(CH2)4NH3]2P4O12·2H2O
Auteurs : E. H. Soumhi [Tunisie] ; I. Saadoune [Tunisie] ; A. Driss [Tunisie] ; T. Jouini [Tunisie]Source :
- European Journal of Solid State and Inorganic Chemistry [ 0992-4361 ] ; 1998.
English descriptors
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Abstract
Abstract: After a short survey of what is the present state of the cyclophosphates associated with the organic molecule NH2(CH2)4NH2, we report chemical preparation and crystal structure for a new example of such compounds. [NH3(CH2)4NH3]2P4O12.2H2O is monoclinic (S.G. : P21/n), with Z = 2 and the following unit-cell parameters : a = 7.6728(8) Å, b = 18.962(3) Å, c = 7.9789(9) Å β = 111.751(9)°. Bidimensional layer arrangement of P4O12 rings connected to the water molecules thanks to weak H-bonds run parallel to the ab plane. The organic groupements located between these inorganic planes perform the three-dimensional cohesion by NH····O hydrogen bonds.
Url:
DOI: 10.1016/S0992-4361(99)80004-6
Affiliations:
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[NH3(CH2)4NH3]2P4O12.2H2O is monoclinic (S.G. : P21/n), with Z = 2 and the following unit-cell parameters : a = 7.6728(8) Å, b = 18.962(3) Å, c = 7.9789(9) Å β = 111.751(9)°. Bidimensional layer arrangement of P4O12 rings connected to the water molecules thanks to weak H-bonds run parallel to the ab plane. The organic groupements located between these inorganic planes perform the three-dimensional cohesion by NH····O hydrogen bonds.</div></front></TEI><affiliations><list><country><li>Tunisie</li></country><region><li>Gouvernorat de Tunis</li></region><settlement><li>Tunis</li></settlement></list><tree><country name="Tunisie"><noRegion><name sortKey="Soumhi, E H" sort="Soumhi, E H" uniqKey="Soumhi E" first="E. H." last="Soumhi">E. H. Soumhi</name></noRegion><name sortKey="Driss, A" sort="Driss, A" uniqKey="Driss A" first="A." last="Driss">A. Driss</name><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">T. 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